Zhongyuan Institute of Technology prepares new supercapacitor electrode materials

The reporter learned from the Center for Advanced Materials Research of Zhongyuan University of Technology that the professor of the center, Mi Liwei, led the team to prepare the hollow spheroidal supercapacitor electrode material with high electron and ionic conductivity through the design of molecular structure. Related results have been published in the Journal of Applied Materials and Interfaces.

It is reported that the supercapacitor is limited by the conductivity of the electrode material, so that the reversible electrochemical redox reaction only occurs on the surface of the electrode material, which greatly reduces the utilization of the electrode material.

The researchers succeeded in designing and preparing high-electron and ion-conducting hollow-spheroidal basic nickel-nickel-carbonate electrode materials by self-growth and sacrificial template method, and the abundant metal bonds between the crystal structures provided sufficient electron transport channels. The intercalation of hydroxide and water between their one-dimensional chain crystal structural units provides a guarantee for the rapid transport of ions.

Tests have shown that the basic nickel-carbonate electrode material designed by the researchers exhibits excellent rate performance, specific capacity and long stability. In the case of a 100-fold increase in current density, the capacitor capacity retention rate is as high as 96.2%; at a current density of 20 amps per gram, the specific capacity is as high as 108.3 Farah per gram; at 20 amps per gram, 100,000 cycles, capacity retention Up to 85.8%. Therefore, the supercapacitor electrode material has a good industrial application prospect.


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